The Samsung Gear S3 Frontier is my choice for the best looking Smartwatch out there. It has a distinctive look that shows there was a lot of thought put into making a watch that looks more like a watch, versus some cut-off-the-mill wearable wrist gadget posing as a watch. It comes with a decent black rubber wristband, but if you're looking for more options like leather bands, there are a ton of great options to choose from.
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